Han Jae Hyo, Kwak Minkyoung, Kim Youngsoo, Cheon Jinwoo
Center for Nanomedicine , Institute for Basic Science (IBS) , Seoul 03722 , Republic of Korea.
Chem Rev. 2018 Jul 11;118(13):6151-6188. doi: 10.1021/acs.chemrev.8b00264. Epub 2018 Jun 21.
The precise control in size/thickness, composition, crystal phases, doping, defects, and surface properties of two-dimensional (2D) layered transition metal chalcogenide (TMC) is important for the investigation of interwoven relationship between structures, functions, and practical applications. Of the multiple synthetic routes, solution-based top-down and bottom-up chemical methods have been uniquely important for their potential to control the size and composition at the molecular level in addition to their scalability, competitive production cost, and solution processability. Here, we introduce an overview of the recent advances in the solution-based preparation routes of 2D layered TMC nanostructures along with important scientific developments.
精确控制二维(2D)层状过渡金属硫族化合物(TMC)的尺寸/厚度、组成、晶相、掺杂、缺陷和表面性质,对于研究结构、功能和实际应用之间的交织关系至关重要。在多种合成路线中,基于溶液的自上而下和自下而上的化学方法具有独特的重要性,因为它们除了具有可扩展性、具有竞争力的生产成本和溶液可加工性之外,还具有在分子水平上控制尺寸和组成的潜力。在此,我们介绍基于溶液的二维层状TMC纳米结构制备路线的最新进展概述以及重要的科学进展。