蓝光促进芳基重氮乙酸酯的光解。
Blue light-promoted photolysis of aryldiazoacetates.
作者信息
Jurberg Igor D, Davies Huw M L
机构信息
Department of Chemistry , Emory University , 1515 Dickey Drive , Atlanta , Georgia 30322 , USA.
Institute of Chemistry , State University of Campinas , Rua Monteiro Lobato 270 , Campinas , São Paulo 13083-970 , Brazil . Email:
出版信息
Chem Sci. 2018 May 22;9(22):5112-5118. doi: 10.1039/c8sc01165f. eCollection 2018 Jun 14.
Abstract
Aryldiazoacetates can undergo photolysis under blue light irradiation (460-490 nm) at room temperature and under air in the presence of numerous trapping agents, such as styrene, carboxylic acids, amines, alkanes and arenes, thus providing a straighforward and general platform for their mild functionalization.
摘要
芳基重氮乙酸酯在室温下、空气中以及众多捕获剂（如苯乙烯、羧酸、胺、烷烃和芳烃）存在的情况下，在蓝光照射（460 - 490 nm）下可发生光解，从而为其温和官能化提供了一个直接且通用的平台。
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