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蓝光促进芳基重氮乙酸酯的光解。

Blue light-promoted photolysis of aryldiazoacetates.

作者信息

Jurberg Igor D, Davies Huw M L

机构信息

Department of Chemistry , Emory University , 1515 Dickey Drive , Atlanta , Georgia 30322 , USA.

Institute of Chemistry , State University of Campinas , Rua Monteiro Lobato 270 , Campinas , São Paulo 13083-970 , Brazil . Email:

出版信息

Chem Sci. 2018 May 22;9(22):5112-5118. doi: 10.1039/c8sc01165f. eCollection 2018 Jun 14.

DOI:10.1039/c8sc01165f
PMID:29938043
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5994880/
Abstract

Aryldiazoacetates can undergo photolysis under blue light irradiation (460-490 nm) at room temperature and under air in the presence of numerous trapping agents, such as styrene, carboxylic acids, amines, alkanes and arenes, thus providing a straighforward and general platform for their mild functionalization.

摘要

芳基重氮乙酸酯在室温下、空气中以及众多捕获剂（如苯乙烯、羧酸、胺、烷烃和芳烃）存在的情况下，在蓝光照射（460 - 490 nm）下可发生光解，从而为其温和官能化提供了一个直接且通用的平台。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/22c2d5d31c09/c8sc01165f-s9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/0fe4bf6fa58c/c8sc01165f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/fa82987b1edf/c8sc01165f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/46f1636c769b/c8sc01165f-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/b98d47108e49/c8sc01165f-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/73b1ae953932/c8sc01165f-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/b164223a3722/c8sc01165f-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/7ed34bc30293/c8sc01165f-s6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/b114496839e8/c8sc01165f-s7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/7c78db95629c/c8sc01165f-s8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/22c2d5d31c09/c8sc01165f-s9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/0fe4bf6fa58c/c8sc01165f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/fa82987b1edf/c8sc01165f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/46f1636c769b/c8sc01165f-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/b98d47108e49/c8sc01165f-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/73b1ae953932/c8sc01165f-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/b164223a3722/c8sc01165f-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/7ed34bc30293/c8sc01165f-s6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/b114496839e8/c8sc01165f-s7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/7c78db95629c/c8sc01165f-s8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe5/5994880/22c2d5d31c09/c8sc01165f-s9.jpg

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