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使用钝化氧化锡作为电子传输层的高效平面钙钛矿太阳能电池。

Efficient Planar Perovskite Solar Cells Using Passivated Tin Oxide as an Electron Transport Layer.

作者信息

Lee Yonghui, Lee Seunghwan, Seo Gabseok, Paek Sanghyun, Cho Kyung Taek, Huckaba Aron J, Calizzi Marco, Choi Dong-Won, Park Jin-Seong, Lee Dongwook, Lee Hyo Joong, Asiri Abdullah M, Nazeeruddin Mohammad Khaja

机构信息

Group for Molecular Engineering of Functional Materials Ecole Polytechnique Fédérale de Lausanne CH-1951 Sion Switzerland.

Division of Materials Science and Engineering Hanyang University 222 Wangsimni-ro Seongdong-gu Seoul 133-791 Korea.

出版信息

Adv Sci (Weinh). 2018 Mar 25;5(6):1800130. doi: 10.1002/advs.201800130. eCollection 2018 Jun.

DOI:10.1002/advs.201800130
PMID:29938189
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6010698/
Abstract

Planar perovskite solar cells using low-temperature atomic layer deposition (ALD) of the SnO electron transporting layer (ETL), with excellent electron extraction and hole-blocking ability, offer significant advantages compared with high-temperature deposition methods. The optical, chemical, and electrical properties of the ALD SnO layer and its influence on the device performance are investigated. It is found that surface passivation of SnO is essential to reduce charge recombination at the perovskite and ETL interface and show that the fabricated planar perovskite solar cells exhibit high reproducibility, stability, and power conversion efficiency of 20%.

摘要

采用低温原子层沉积（ALD）法制备氧化锡电子传输层（ETL）的平面钙钛矿太阳能电池，具有优异的电子提取和空穴阻挡能力，与高温沉积方法相比具有显著优势。研究了ALD氧化锡层的光学、化学和电学性质及其对器件性能的影响。发现氧化锡的表面钝化对于减少钙钛矿与ETL界面处的电荷复合至关重要，并且所制备的平面钙钛矿太阳能电池具有高重现性、稳定性，功率转换效率达20%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/7c5b55e8d738/ADVS-5-1800130-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/1104e467b039/ADVS-5-1800130-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/747bf8aacc05/ADVS-5-1800130-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/ce4e8566cf0b/ADVS-5-1800130-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/bb216fcbfb25/ADVS-5-1800130-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/7c5b55e8d738/ADVS-5-1800130-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/1104e467b039/ADVS-5-1800130-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/747bf8aacc05/ADVS-5-1800130-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/ce4e8566cf0b/ADVS-5-1800130-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/bb216fcbfb25/ADVS-5-1800130-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62fe/6010698/7c5b55e8d738/ADVS-5-1800130-g005.jpg

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Incomplete elimination of precursor ligands during atomic layer deposition of zinc-oxide, tin-oxide, and zinc-tin-oxide.在原子层沉积氧化锌、氧化锡和锌锡氧化物过程中，前体配体未完全消除。
J Chem Phys. 2017 Feb 7;146(5):052802. doi: 10.1063/1.4961459.
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Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency.
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Nanomaterials (Basel). 2023 May 24;13(11):1724. doi: 10.3390/nano13111724.
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Moderate temperature deposition of RF magnetron sputtered SnO-based electron transporting layer for triple cation perovskite solar cells.射频磁控溅射 SnO 基电子传输层的中温沉积用于三阳离子钙钛矿太阳能电池。
Sci Rep. 2023 Jun 5;13(1):9100. doi: 10.1038/s41598-023-35651-1.
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Effect of guanidinium chloride in eliminating O electron extraction barrier on a SnO surface to enhance the efficiency of perovskite solar cells.氯化铵消除SnO表面O电子提取势垒对提高钙钛矿太阳能电池效率的影响。
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Inorganic Materials by Atomic Layer Deposition for Perovskite Solar Cells.用于钙钛矿太阳能电池的原子层沉积无机材料
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