Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon, Hong Kong S.A.R., P. R. China.
Chem Soc Rev. 2018 Jul 17;47(14):5234-5265. doi: 10.1039/c8cs00002f.
Many treatments of energy transfer (ET) phenomena in current literature employ incorrect arguments and formulae and are not quantitative enough. This is unfortunate because we witness important breakthroughs from ET experiments in nanoscience. This review aims to clarify basic principles by focusing upon Förster-Dexter electric dipole-electric dipole (ED-ED) ET. The roles of ET in upconversion, downconversion and the antenna effect are described and the clichés and simple formulae to be avoided in ET studies are highlighted with alternative treatments provided.
目前文献中许多关于能量转移(ET)现象的处理方法都使用了不正确的论据和公式,而且不够定量。这很不幸,因为我们从纳米科学中的 ET 实验中看到了重要的突破。这篇综述旨在通过聚焦于福斯特-德克斯特电偶极-电偶极(ED-ED)ET,阐明基本原理。描述了 ET 在上转换、下转换和天线效应中的作用,并强调了在 ET 研究中应避免的陈词滥调和简单公式,并提供了替代处理方法。