Stikute Agnese, Skestere Karina, Mierina Inese, Mishnev Anatoly, Jure Mara
Institute of Technology of Organic Chemistry, Faculty of Materials Science and Applied Chemistry, Riga Technical University, P. Valdena Str. 3/7, Riga, LV-1048, Latvia.
Latvian Institute of Organic Synthesis, Aizkraukles Str. 21, Riga, LV-1006, Latvia.
Acta Crystallogr E Crystallogr Commun. 2018 May 15;74(Pt 6):796-798. doi: 10.1107/S2056989018006941. eCollection 2018 Jun 1.
In the title compound, CHO, a new starting compound for the synthesis of various heterocycles, the partially saturated six-membered ring adopts a sofa conformation. An intra-molecular O-H⋯O hydrogen bond is observed in the guaiacol residue. In the crystal, mol-ecules are assembled into a sheet structure parallel to the plane O-H⋯O hydrogen bonds. The hydrogen-bond pattern is described by an (28) graph-set motif. The sheets are further linked by C-H⋯O hydrogen bonds into a three-dimensional network.
在标题化合物CHO（一种用于合成各种杂环的新型起始化合物）中，部分饱和的六元环呈沙发构象。在愈创木酚残基中观察到分子内O-H⋯O氢键。在晶体中，分子通过O-H⋯O氢键组装成平行于 平面的片状结构。氢键模式由（28）图集基序描述。这些片层通过C-H⋯O氢键进一步连接成三维网络。
