Department of Chemistry , Aliah University , New Town , Kolkata 700 156 , India.
Department of Physics , Jadavpur University , Jadavpur , Kolkata 700 032 , India.
Inorg Chem. 2018 Jul 16;57(14):8029-8032. doi: 10.1021/acs.inorgchem.8b00833. Epub 2018 Jun 28.
A pair of 4-(1-naphthylvinyl)pyridine (4-nvp) ligands has been successfully aligned in head-to-tail fashion in a one-dimensional (1D) double chain ladder polymer [Cd(adc)(4-nvp)(HO)] (1; Hadc = acetylenedicarboxylic acid) that undergoes a photochemical [2 + 2] cycloaddition reaction accompanied by single-crystal to single-crystal (SCSC) structural transformation from a 1D chain to a 2D layer structure. These structural changes have a significant impact on the conductivity and Schottky nature of the compound.
一对 4-(1-萘基乙烯基)吡啶(4-nvp)配体在一维(1D)双链梯聚合物[Cd(adc)(4-nvp)(HO)]（1；Hadc=丙二炔二羧酸）中成功地以头尾相连的方式排列，该聚合物经历光化学[2+2]环加成反应，伴随着从 1D 链到 2D 层结构的单晶到单晶（SCSC）结构转变。这些结构变化对化合物的导电性和肖特基性质有重大影响。
