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源自生物炼制副产品的自交联硬质泡沫

Auto-Crosslinked Rigid Foams Derived from Biorefinery Byproducts.

作者信息

Tosi Pierluigi, van Klink Gerard P M, Celzard Alain, Fierro Vanessa, Vincent Luc, de Jong Ed, Mija Alice

机构信息

Institute of Chemistry of Nice, UMR CNRS 7272, Université Côte d'Azur, University of Nice Sophia Antipolis, Parc Valrose, 06108, Nice cedex 2, France.

Avantium Chemicals B.V., Zekeringstraat 29, 1014 BV, Amsterdam, The Netherlands.

出版信息

ChemSusChem. 2018 Aug 22;11(16):2797-2809. doi: 10.1002/cssc.201800778. Epub 2018 Jul 25.

DOI:10.1002/cssc.201800778
PMID:29956889
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6392144/
Abstract

A new macroporous foam-like material is presented based on autocross-linking humins, an industrial biorefinery byproduct. Humins foams are obtained by a simple heating process, without any pretreatment and with high control of morphology, porosity, and carbon content. Untreated humins have been characterized by GC, ultra-performance liquid chromatography (UPLC), elemental analysis, and FTIR, whereas the mechanism of foaming was elucidated by a combination of thermal and rheological analyses. A preliminary screening of conditions was conducted to identify the parameters controlling this foaming process. A foam was produced in a controlled way with open and/or closed cells with cell diameters between 0.2 and 3.5 mm. Humins foams were characterized by Raman spectroscopy, FTIR, SEM, nitrogen adsorption, pycnometry, and mechanical tests. The results show that, based on humins, it is possible to obtain porous materials with controlled architectures and a range of parameters that can be tailored, depending on the foreseen applications.

摘要

本文介绍了一种基于自交联腐殖质（一种工业生物精炼副产品）的新型大孔泡沫状材料。腐殖质泡沫通过简单的加热过程获得，无需任何预处理，且能高度控制其形态、孔隙率和碳含量。未处理的腐殖质已通过气相色谱（GC）、超高效液相色谱（UPLC）、元素分析和傅里叶变换红外光谱（FTIR）进行了表征，而发泡机理则通过热分析和流变分析相结合的方式得以阐明。进行了条件的初步筛选，以确定控制该发泡过程的参数。以可控方式制备出了具有开孔和/或闭孔、泡孔直径在0.2至3.5毫米之间的泡沫。腐殖质泡沫通过拉曼光谱、FTIR、扫描电子显微镜（SEM）、氮气吸附、比重瓶法和力学测试进行了表征。结果表明，基于腐殖质能够获得具有可控结构且一系列参数可根据预期应用进行定制的多孔材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/3a790529d476/CSSC-11-2797-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/8e6848063015/CSSC-11-2797-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/fb1521c20676/CSSC-11-2797-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/559fdab691b2/CSSC-11-2797-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/100d65e1845b/CSSC-11-2797-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/62e2d82bfd88/CSSC-11-2797-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/cc4885ba4882/CSSC-11-2797-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/27cafb93d321/CSSC-11-2797-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/327577e56d1c/CSSC-11-2797-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/c4a13de968a5/CSSC-11-2797-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/3a790529d476/CSSC-11-2797-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/8e6848063015/CSSC-11-2797-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/fb1521c20676/CSSC-11-2797-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/559fdab691b2/CSSC-11-2797-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/100d65e1845b/CSSC-11-2797-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/62e2d82bfd88/CSSC-11-2797-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/cc4885ba4882/CSSC-11-2797-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/27cafb93d321/CSSC-11-2797-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/327577e56d1c/CSSC-11-2797-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/c4a13de968a5/CSSC-11-2797-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/00bc/6392144/3a790529d476/CSSC-11-2797-g009.jpg

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