Yang Zhi-Hao, He Ming-Jing, Yang Ting, Lu Jun-Feng, Wei Shi-Qiang
College of Resources and Environment, Southwest University, Chongqing 400715, China.
Chongqing Key Laboratory of Agricultural Resources and Environment Research, Chongqing 400716, China.
Huan Jing Ke Xue. 2018 Jul 8;39(7):3358-3364. doi: 10.13227/j.hjkx.201711092.
In total, 66 soil samples were collected from five different urban functional areas in Chongqing, and the concentration levels of phthalate esters (PAEs) were analyzed using ultra-high performance liquid chromatography-quadrupole time-of-flight mass spectrometry (UPLC-Q-TOF-MS). Meanwhile, the composition and characteristics of PAEs were discussed, along with their possible sources, through correlation analysis and principal component analysis. The results showed that the concentrations of ∑ ranged from 93.1-312 ng·g dry weight, which is at the low end of the worldwide figure. DEHP, DBP, and DIBP were the dominant compounds, contributing 87.4%-92.9% of the total ∑. DEHP was the most abundant PAE congener, responsible for 52.4% of the total ∑. Through correlation analysis, it was noted that PAEs with similar molecular weight were more likely to show a significant relationship with each other, which suggested that these PAEs may share a similar source. According to the principal component analysis, DBP, DIBP, and DEHP had a similar source, while BBP and DnOP strongly correlated with each other. Compared to other studies, relatively low PAE concentrations were apparently observed in this study, but the potential human risk via exposure to these compounds should also been considered.
总共从重庆五个不同的城市功能区采集了66份土壤样本,并使用超高效液相色谱-四极杆飞行时间质谱仪(UPLC-Q-TOF-MS)分析了邻苯二甲酸酯(PAEs)的浓度水平。同时,通过相关性分析和主成分分析,讨论了PAEs的组成和特征及其可能的来源。结果表明,∑的浓度范围为93.1 - 312 ng·g干重,处于全球范围内的较低水平。邻苯二甲酸二(2-乙基己基)酯(DEHP)、邻苯二甲酸二丁酯(DBP)和邻苯二甲酸二异丁酯(DIBP)是主要化合物,占总∑的87.4% - 92.9%。DEHP是最丰富的PAE同系物,占总∑的52.4%。通过相关性分析发现,分子量相似的PAEs彼此之间更有可能呈现显著关系,这表明这些PAEs可能具有相似的来源。根据主成分分析,DBP、DIBP和DEHP有相似的来源,而邻苯二甲酸丁苄酯(BBP)和邻苯二甲酸二正辛酯(DnOP)彼此之间相关性很强。与其他研究相比,本研究中明显观察到PAE浓度相对较低,但也应考虑通过接触这些化合物对人类造成的潜在风险。