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[南宁市环境介质中多环芳烃的分布特征]

[Distribution Characteristics of Polycyclic Aromatic Hydrocarbons in Environmental Media in Nanning City].

作者信息

Miao Ying, Kong Xiang-Sheng

机构信息

Key Laboratory of Karst Dynamics, Ministry of Land and Resources & Guangxi, Institute of Karst Geology, Chinese Academy of Geological Sciences, Guilin 541004, China.

出版信息

Huan Jing Ke Xue. 2016 Nov 8;37(11):4333-4340. doi: 10.13227/j.hjkx.201603240.

Abstract

In order to understand the contamination characteristics of polycyclic aromatic hydrocarbons in different environmental media, the authors collected samples of air, atmospheric dry and wet depositions, soil and groundwater in winter and summer in Nanning, using component spectra of 16 kinds of polycyclic aromatic hydrocarbons, combining with the physical and chemical properties, analyzed concentration, composition and distribution characteristics of the PAHs in different environment media, the results showed that PAHs with 2 to 3 rings were dominant in the air and atmospheric dry and wet depositions, and ∑ PAHs in winter were higher than in summer because of the seasonal differences. And PAHs with 2 to 3 rings were dominant in soil, too. Distribution difference of soil particle diameter was the main reason for the PAHs distribution characteristics in different horizons. And species of PAHs in groundwater were fewer, with lower concentrations, which showed that soil vadose zone could entrap more PAHs. The mass fraction of 16 kinds of polycyclic aromatic hydrocarbons in different environmental media presented a decreasing trend from low rings to high rings, and the distribution characteristics of PAHs with 2 to 3 rings and 5 to 6 rings in different environmental media in two areas in winter and summer had good consistency, but also had certain differences because of the physical and chemical properties of PAHs, hydro-geological conditions, urban pollution, weather conditions, etc.

摘要

为了解多环芳烃在不同环境介质中的污染特征,作者于冬季和夏季在南宁采集了空气、大气干湿沉降物、土壤和地下水样本,利用16种多环芳烃的组分光谱,结合物理和化学性质,分析了不同环境介质中多环芳烃的浓度、组成和分布特征,结果表明,在空气和大气干湿沉降物中,2至3环的多环芳烃占主导地位,由于季节差异,冬季的∑多环芳烃高于夏季。土壤中也是2至3环的多环芳烃占主导地位。土壤粒径分布差异是不同土层中多环芳烃分布特征的主要原因。地下水中多环芳烃的种类较少,浓度较低,这表明土壤包气带能够截留更多的多环芳烃。不同环境介质中16种多环芳烃的质量分数呈现出从低环到高环递减的趋势,两个地区冬夏季不同环境介质中2至3环和5至6环多环芳烃的分布特征具有较好的一致性,但由于多环芳烃的物理化学性质、水文地质条件、城市污染、气象条件等因素,也存在一定差异。

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