烯二炔与炔烃的[3 + 2]环加成反应。
[3 + 2]-Cycloaddition reaction of sydnones with alkynes.
作者信息
Hladíková Veronika, Váňa Jiří, Hanusek Jiří
机构信息
Institute of Organic Chemistry and Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic.
出版信息
Beilstein J Org Chem. 2018 Jun 5;14:1317-1348. doi: 10.3762/bjoc.14.113. eCollection 2018.
This review covers all known examples of [3 + 2]-cycloaddition between sydnones and both terminal as well as internal alkynes/cycloalkynes taken from literature since its discovery by Huisgen in 1962 up to the current date. Except enumeration of synthetic applications it also covers mechanistic studies, catalysis, effects of substituents and reaction conditions influencing reaction rate and regioselectivity.
本综述涵盖了自1962年惠斯根发现以来，文献中报道的烯酮与末端炔烃、内炔烃/环炔烃之间所有已知的[3 + 2]环加成反应实例，直至当前日期。除了列举合成应用外，还涵盖了机理研究、催化、取代基的影响以及影响反应速率和区域选择性的反应条件。
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