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受质谱启发通过加热降解饮用水中的消毒副产物2,6-二氯-1,4-苯醌

Mass Spectrometry-Inspired Degradation of Disinfection By-Product, 2,6-Dichloro-1,4-benzoquinone, in Drinking Water by Heating.

作者信息

Pei Jiying, Zhang Ruiling, Hsu Chengchih, Wang Yinghui

机构信息

School of Marine Sciences, Guangxi University, Nanning 53004, P. R. China.

Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan.

出版信息

Mass Spectrom (Tokyo). 2018;7(1):A0068. doi: 10.5702/massspectrometry.A0068. Epub 2018 Jun 29.

DOI:10.5702/massspectrometry.A0068
PMID:29977665
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6018241/
Abstract

2,6-Dichloro-1,4-benzoquinone (DCBQ), a highly toxic and carcinogenic disinfection by-product, was degraded during the electrospray process by elevating the source temperature. This unexpected finding inspired us to use heating to degrade DCBQs in drinking water. The results show that about 99% of DCBQs in the drinking water were degraded in one minute by heating to 100°C with room light irradiation. Therefore, a conclusion can be drawn that heating enables the degradation of DCBQs in drinking water.

摘要

2,6-二氯-1,4-苯醌(DCBQ)是一种剧毒且致癌的消毒副产物,在电喷雾过程中通过提高源温度而被降解。这一意外发现促使我们利用加热来降解饮用水中的DCBQ。结果表明,在室温光照下将饮用水加热到100°C,一分钟内约99%的DCBQ被降解。因此,可以得出结论,加热能够使饮用水中的DCBQ降解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/7611182435a9/massspectrometry-7-1-A0068-figure04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/c4e5a31160ba/massspectrometry-7-1-A0068-figure01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/a56ce4ddd2dd/massspectrometry-7-1-A0068-figure02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/6ce029f7c13e/massspectrometry-7-1-A0068-figure03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/7611182435a9/massspectrometry-7-1-A0068-figure04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/c4e5a31160ba/massspectrometry-7-1-A0068-figure01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/a56ce4ddd2dd/massspectrometry-7-1-A0068-figure02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/6ce029f7c13e/massspectrometry-7-1-A0068-figure03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dce/6018241/7611182435a9/massspectrometry-7-1-A0068-figure04.jpg

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本文引用的文献

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Environ Sci Technol. 2013 May 7;47(9):4426-33. doi: 10.1021/es305044k. Epub 2013 Apr 22.
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Occurrence and formation of chloro- and bromo-benzoquinones during drinking water disinfection.饮用水消毒过程中氯代和溴代苯醌的生成与形成。
Water Res. 2012 Sep 15;46(14):4351-60. doi: 10.1016/j.watres.2012.05.032. Epub 2012 Jun 2.
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Potential carcinogenic hazards of non-regulated disinfection by-products: haloquinones, halo-cyclopentene and cyclohexene derivatives, N-halamines, halonitriles, and heterocyclic amines.潜在致癌危害的不受管制的消毒副产物:卤醌、卤环戊烯和环己烯衍生物、N-卤代胺、卤代腈和杂环胺。
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Detoxifying carcinogenic polyhalogenated quinones by hydroxamic acids via an unusual double Lossen rearrangement mechanism.通过羟肟酸的不寻常的双 Lossen 重排机制解毒致癌多卤代醌。
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