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金属有机框架材料:在能量转换和存储方面的进展和前景。

Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage.

机构信息

Department of Energy Engineering, Hanyang University, Seoul, 133-791, Republic of Korea.

出版信息

Adv Mater. 2018 Sep;30(39):e1705146. doi: 10.1002/adma.201705146. Epub 2018 Jul 8.

Abstract

Exploring new materials with high efficiency and durability is the major requirement in the field of sustainable energy conversion and storage systems. Numerous techniques have been developed in last three decades to enhance the efficiency of the catalyst systems, control over the composition, structure, surface area, pore size, and moreover morphology of the particles. In this respect, metal organic framework (MOF) derived catalysts are emerged as the finest materials with tunable properties and activities for the energy conversion and storage. Recently, several nano- or microstructures of metal oxides, chalcogenides, phosphides, nitrides, carbides, alloys, carbon materials, or their hybrids are explored for the electrochemical energy conversion like oxygen evolution, hydrogen evolution, oxygen reduction, or battery materials. Interest on the efficient energy storage system is also growing looking at the practical applications. Though, several reviews are available on the synthesis and application of MOF and MOF derived materials, their applications for the electrochemical energy conversion and storage is totally a new field of research and developed recently. This review focuses on the systematic design of the materials from MOF and control over their inherent properties to enhance the electrochemical performances.

摘要

探索高效且耐用的新材料是可持续能源转换和存储系统领域的主要要求。在过去的三十年中,已经开发出了许多技术来提高催化剂系统的效率,控制组成、结构、表面积、孔径,甚至颗粒的形态。在这方面,金属有机骨架(MOF)衍生的催化剂作为具有可调特性和活性的最佳材料,用于能源转换和存储。最近,已经探索了几种纳米或微结构的金属氧化物、硫属化物、磷化物、氮化物、碳化物、合金、碳材料或它们的混合物,用于电化学能量转换,如氧气析出、氢气析出、氧气还原或电池材料。考虑到实际应用,对高效储能系统的兴趣也在增长。尽管已经有关于 MOF 和 MOF 衍生材料的合成和应用的综述,但它们在电化学能量转换和存储中的应用完全是一个新的研究领域,最近才得到发展。本文综述了从 MOF 进行材料的系统设计及其固有性能的控制,以提高电化学性能。

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