International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan.
Department of Chemical Engineering, Monash University, Clayton, VIC, 3800, Australia.
Adv Mater. 2017 Mar;29(12). doi: 10.1002/adma.201604898. Epub 2016 Dec 27.
The emergence of metal-organic frameworks (MOFs) as a new class of crystalline porous materials is attracting considerable attention in many fields such as catalysis, energy storage and conversion, sensors, and environmental remediation due to their controllable composition, structure and pore size. MOFs are versatile precursors for the preparation of various forms of nanomaterials as well as new multifunctional nanocomposites/hybrids, which exhibit superior functional properties compared to the individual components assembling the composites. This review provides an overview of recent developments achieved in the fabrication of porous MOF-derived nanostructures including carbons, metal oxides, metal chalcogenides (metal sulfides and selenides), metal carbides, metal phosphides and their composites. Finally, the challenges and future trends and prospects associated with the development of MOF-derived nanomaterials are also examined.
金属-有机骨架（MOFs）作为一类新型的结晶多孔材料，由于其组成、结构和孔径的可控性，在催化、储能与转化、传感器和环境修复等诸多领域引起了相当大的关注。MOFs 是制备各种形式纳米材料以及新型多功能纳米复合材料/杂化材料的多功能前体，与组装复合材料的各个成分相比，它们表现出优异的功能特性。本综述概述了在多孔 MOF 衍生纳米结构（包括碳、金属氧化物、金属硫属化物（金属硫化物和硒化物）、金属碳化物、金属磷化物及其复合材料）的制备方面取得的最新进展。最后，还考察了与 MOF 衍生纳米材料的发展相关的挑战以及未来的趋势和前景。
