Organic Carbonyl Compounds for Sodium-Ion Batteries: Recent Progress and Future Perspectives.

Sodium-organic batteries, which use organic materials as the electrodes in sodium-ion batteries, are an attractive alternative to conventional lithium-ion batteries for next-generation sustainable and versatile energy storage devices owing to the abundant sodium resources and environmental friendly features. However, organics used in sodium-ion batteries also encounter some issues such as low redox potential, high solubility in the electrolyte, and low conductivity. In response, altering the aromatic system/attaching electron-withdrawing groups, constructing polymers, and incorporating a conductive matrix are effective strategies. This review summarizes and briefly discusses recent organic carbonyl compounds for sodium-organic batteries from the viewpoint of function-oriented design, including function evolution from small-molecule compounds to polymers, then composites, and finally flexible electrodes. In particular, as a timely overview, carbonyl-based organic flexible electrodes for sodium-organic batteries are also highlighted for the first time.