用于环状肟醚片段化-炔基化级联反应的精细有机光氧化还原催化剂

Fine-tuned organic photoredox catalysts for fragmentation-alkynylation cascades of cyclic oxime ethers.

作者信息

Le Vaillant Franck, Garreau Marion, Nicolai Stefano, Gryn'ova Ganna, Corminboeuf Clemence, Waser Jerome

机构信息

Laboratory of Catalysis and Organic Synthesis , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland . Email:

Laboratory for Computational Molecular Design , Institut des Sciences et Ingénierie Chimique , Ecole Polytechnique Fédérale de Lausanne , Ch-1015 , Lausanne , Switzerland.

出版信息

Chem Sci. 2018 May 30;9(27):5883-5889. doi: 10.1039/c8sc01818a. eCollection 2018 Jul 21.

Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated oxidative ring opening of cyclic alkylketone oxime ethers. The redox properties of the dyes were determined by both cyclic voltammetry and computation and covered an existing gap in the oxidation potential of photoredox organocatalysts.