Li Ming, Ma Chuang, Liu Xiong, Su Jun, Cui Xiaofeng, He Yunbin
Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials , Key Laboratory for the Synthesis and Application of Organic Functional Molecules , Ministry of Education , Hubei Key Laboratory of Polymer Materials , College of Chemistry and Chemical Engineering , Hubei University , Wuhan 430062 , People's Republic of China . Email:
Carl Zeiss Microscopy GmbH , Carl-Zeiss-Str. 22, Oberkcohen , 73447 , Germany.
Chem Sci. 2018 Jun 12;9(27):5912-5918. doi: 10.1039/c8sc01439f. eCollection 2018 Jul 21.
Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar-layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P). Our research may provide a new approach for the synthesis of various 2D materials.
二维（2D）材料的合成主要依赖于界面模板、层状晶体的剥离和表面活性剂辅助。在此，我们实现了二维纳米反应器中的另一种聚合策略。作为该策略的应用，在一种新型柱层金属有机框架（MOF）内构建了二维纳米反应器，并在该纳米反应器中由白磷（P）合成了一种适度稳定的二维磷材料。我们的研究可能为各种二维材料的合成提供一种新方法。
