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具有增强场电子发射性能的锂掺杂纳米晶金刚石薄膜的低温合成

Low Temperature Synthesis of Lithium-Doped Nanocrystalline Diamond Films with Enhanced Field Electron Emission Properties.

作者信息

Sankaran Kamatchi Jothiramalingam, Panda Kalpataru, Hsieh Ping-Yen, Pobedinskas Paulius, Park Jeong Young, Van Bael Marlies K, Tai Nyan-Hwa, Lin I-Nan, Haenen Ken

机构信息

Institute for Materials Research (IMO), Hasselt University, 3590 Diepenbeek, Belgium.

IMOMEC, IMEC vzw, 3590 Diepenbeek, Belgium.

出版信息

Nanomaterials (Basel). 2018 Aug 24;8(9):653. doi: 10.3390/nano8090653.

DOI:10.3390/nano8090653
PMID:30149533
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6164399/
Abstract

Low temperature (350 °C) grown conductive nanocrystalline diamond (NCD) films were realized by lithium diffusion from Cr-coated lithium niobate substrates (Cr/LNO). The NCD/Cr/LNO films showed a low resistivity of 0.01 Ω·cm and excellent field electron emission characteristics, viz. a low turn-on field of 2.3 V/µm, a high-current density of 11.0 mA/cm² (at 4.9 V/m), a large field enhancement factor of 1670, and a life-time stability of 445 min (at 3.0 mA/cm²). The low temperature deposition process combined with the excellent electrical characteristics offers a new prospective for applications based on temperature sensitive materials.

摘要

通过从涂有铬的铌酸锂衬底(Cr/LNO)进行锂扩散,实现了低温(350°C)生长的导电纳米晶金刚石(NCD)薄膜。NCD/Cr/LNO薄膜表现出0.01Ω·cm的低电阻率和优异的场电子发射特性,即2.3V/μm的低开启场、11.0mA/cm²(在4.9V/μm时)的高电流密度、1670的大场增强因子以及445分钟(在3.0mA/cm²时)的寿命稳定性。低温沉积工艺与优异的电学特性相结合,为基于温度敏感材料的应用提供了新的前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f60/6164399/a5d94f146f53/nanomaterials-08-00653-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f60/6164399/457f06f27564/nanomaterials-08-00653-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f60/6164399/8025fd1b4326/nanomaterials-08-00653-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f60/6164399/a5d94f146f53/nanomaterials-08-00653-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f60/6164399/457f06f27564/nanomaterials-08-00653-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f60/6164399/8025fd1b4326/nanomaterials-08-00653-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f60/6164399/a5d94f146f53/nanomaterials-08-00653-g003.jpg

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本文引用的文献

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ACS Omega. 2018 Aug 27;3(8):9956-9965. doi: 10.1021/acsomega.8b01104. eCollection 2018 Aug 31.
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Transport and Field Emission Properties of MoS₂ Bilayers.二硫化钼双层膜的输运和场发射特性
Nanomaterials (Basel). 2018 Mar 8;8(3):151. doi: 10.3390/nano8030151.
3
Self-organized multi-layered graphene-boron-doped diamond hybrid nanowalls for high-performance electron emission devices.
自组织多层石墨烯-硼掺杂金刚石杂化纳米墙用于高性能电子发射器件。
Nanoscale. 2018 Jan 18;10(3):1345-1355. doi: 10.1039/c7nr06774g.
4
Locally Resolved Electron Emission Area and Unified View of Field Emission from Ultrananocrystalline Diamond Films.局域电子发射面积与超纳米金刚石薄膜场发射的统一观点。
ACS Appl Mater Interfaces. 2017 Sep 27;9(38):33229-33237. doi: 10.1021/acsami.7b07062. Epub 2017 Sep 13.
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Highly Conductive Diamond-Graphite Nanohybrid Films with Enhanced Electron Field Emission and Microplasma Illumination Properties.具有增强电子场发射和微等离子体照明特性的高导电性金刚石-石墨纳米混合薄膜。
ACS Appl Mater Interfaces. 2015 Jul 1;7(25):14035-42. doi: 10.1021/acsami.5b03166. Epub 2015 Jun 22.
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Nanodiamonds for field emission: state of the art.用于场发射的纳米金刚石:现状
Nanoscale. 2015 Mar 12;7(12):5094-114. doi: 10.1039/c4nr07171a.