Department of Materials Science, Fudan University, Shanghai, 200438, China.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, and Laboratory of Advanced Materials, Fudan University, Shanghai, 200438, China.
Adv Mater. 2018 Oct;30(43):e1803165. doi: 10.1002/adma.201803165. Epub 2018 Aug 30.
Solar radiation, especially ultraviolet (UV) light, is a major hazard for most skin-related cancers. The growing needs for wearable health monitoring systems call for a high-performance real-time UV sensor to prevent skin diseases caused by excess UV exposure. To this end, here a novel self-powered p-CuZnS/n-TiO UV photodetector (PD) with high performance is successfully developed (responsivity of 2.54 mA W at 0 V toward 300 nm). Moreover, by effectively replacing the Ti foil with a thin Ti wire for the anodization process, the conventional planar rigid device is artfully turned into a fiber-shaped flexible and wearable one. The fiber-shaped device shows an outstanding responsivity of 640 A W , external quantum efficiency of 2.3 × 10 %, and photocurrent of ≈4 mA at 3 V, exceeding those of most current UV PDs. Its ultrahigh photocurrent enables it to be easily integrated with commercial electronics to function as a real-time monitor system. Thus, the first real-time wearable UV radiation sensor that reads out ambient UV power density and transmits data to smart phones via wifi is demonstrated. This work not only presents a promising wearable health monitor, but also provides a general strategy for designing and fabricating smart wearable electronic devices.
太阳辐射,尤其是紫外线(UV)光,是大多数皮肤相关癌症的主要危害因素。可穿戴健康监测系统的需求不断增长,需要高性能的实时 UV 传感器来预防因过度暴露于 UV 下而导致的皮肤疾病。为此,我们成功开发了一种新型自供电 p-CuZnS/n-TiO2 UV 光电探测器(PD),具有优异的性能(在 300nm 时 0V 下的响应度为 2.54mA/W)。此外,通过有效用薄钛丝代替钛箔进行阳极氧化处理,将传统的平面刚性器件巧妙地转变成了纤维状的柔性可穿戴器件。纤维状器件的响应度高达 640A/W,外量子效率为 2.3×10%,在 3V 下的光电流约为 4mA,超过了大多数当前的 UV PD。其超高的光电流使其可以轻松与商用电子设备集成,作为实时监测系统使用。因此,展示了第一个实时可穿戴的 UV 辐射传感器,它可以读取环境 UV 功率密度并通过 wifi 将数据传输到智能手机。这项工作不仅提出了一种有前途的可穿戴健康监测器,还为设计和制造智能可穿戴电子设备提供了一种通用策略。