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定制发光稀土混合无机材料的进展。

Advances in tailoring luminescent rare-earth mixed inorganic materials.

机构信息

L3- Luminescent Lanthanide Lab, f-Element Coordination Chemistry, Department of Chemistry, Ghent University, Krijgslaan 281-S3, B-9000 Gent, Belgium.

出版信息

Chem Soc Rev. 2018 Oct 1;47(19):7225-7238. doi: 10.1039/c7cs00893g.

Abstract

This tutorial review focuses on the recent advances in the topic of mixed inorganic materials, specifically rare-earth mixed inorganic materials, which have similar crystal structures to the parent material. In this review we overview the available synthetic methods employed to prepare rare-earth mixed inorganic materials and the common approaches to characterize the differences in the crystal structures when the composition varies within the mixed material. The luminescence properties are investigated after adjusting the composition of the mixed material and doping with suitable lanthanides. We focus on understanding their luminescence performance, which is a crucial step for designing new materials, and exploring their future applications. Last, the possible applications of such rare-earth mixed inorganic materials are also described and further prospects of the exploration of such materials are presented.

摘要

本教程综述重点关注混合无机材料领域的最新进展,特别是与母体材料具有相似晶体结构的稀土混合无机材料。在本综述中,我们概述了制备稀土混合无机材料的可用合成方法,以及在混合材料的组成变化时表征晶体结构差异的常用方法。调整混合材料的组成并掺杂合适的镧系元素后,研究了发光性能。我们专注于了解它们的发光性能,这是设计新材料的关键步骤,并探索它们的未来应用。最后,还描述了此类稀土混合无机材料的可能应用,并提出了对这类材料的进一步探索前景。

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