Karlsruhe Institute of Technology, Institute of Organic Chemistry, Materialwissenschaftliches Zentrum MZE, Straße am Forum 7,, 76131, Karlsruhe, Germany.
Macromol Rapid Commun. 2019 Jan;40(1):e1800524. doi: 10.1002/marc.201800524. Epub 2018 Sep 4.
Plant oils and their derived fatty acids are a highly valuable renewable resource for polymer science. In this review, the use of this renewable resource for the synthesis of nitrogen-containing step-growth polymers, that is, polyamides and polyurethanes, is described. The focus is on the accessible structures of monomers and polymers and thus also the obtainable polymer properties. More importantly, the sustainability of the approaches is discussed and compared to each other where possible, also giving suggestions for future developments.
植物油及其衍生脂肪酸是聚合物科学中极具价值的可再生资源。在这篇综述中，介绍了利用这种可再生资源合成含氮逐步聚合物，即聚酰胺和聚氨酯。重点介绍了单体和聚合物的可获得结构，从而也介绍了可获得的聚合物性能。更重要的是，讨论了这些方法的可持续性，并尽可能进行了相互比较，同时也为未来的发展提出了建议。
