Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie Pvt, Ottawa, ON, Canada K1N 6N5.
Chem Commun (Camb). 2018 Sep 27;54(78):11041-11043. doi: 10.1039/c8cc06019c.
We report the preparation and characterisation of a cocrystal of triphenylphosphine with 1,3,5-trifluoro-2,4,6-triiodobenzene. The structure features a rare example of phosphorus acting as a halogen bond acceptor.
我们报告了三苯基膦与 1,3,5-三氟-2,4,6-三碘苯形成的共晶的制备和性质。该结构的特点是磷作为卤素键受体的罕见例子。