受空气控制辐照下的角型四环酚的选择性氧化去芳构化：具有抗癌性能的蒽环酮型双过氧化物的合成。
Selective Oxidative Dearomatization of Angular Tetracyclic Phenols by Controlled Irradiation under Air: Synthesis of an Angucyclinone-Type Double Peroxide with Anticancer Properties.
机构信息
Departamento de Química Orgánica , Universidad Autónoma de Madrid (UAM) , Cantoblanco , 28049 - Madrid , Spain.
Departamento de Biología , UAM , Cantoblanco , 28049 - Madrid , Spain.
出版信息
Org Lett. 2018 Oct 5;20(19):6094-6098. doi: 10.1021/acs.orglett.8b02515. Epub 2018 Sep 18.
PMID:30226789
Abstract
Angular tetracyclic p-peroxyquinols, p-quinols, and a pentacyclic double peroxide, showing anticancer properties, were synthesized from the corresponding phenols by an environmentally friendly solvent- and wavelength-controlled irradiation under air in the absence of an external photosensitizer.
摘要
角型四元过氧对醌、对苯二酚及一种具有抗癌活性的五元双过氧化物，可由相应的酚在环境友好的溶剂中，于空气氛围下，在无外加光敏剂时，通过光控辐照来合成，所用光源的波长可调控。
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