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基于铕的金属有机骨架作为一种双荧光传感器,用于在水相介质中选择性检测磷酸根阴离子和 Fe 离子。

Europium-Based Metal-Organic Framework as a Dual Luminescence Sensor for the Selective Detection of the Phosphate Anion and Fe Ion in Aqueous Media.

机构信息

School of Chemistry , Indian Institute of Science Education and Research Thiruvananthapuram , Thiruvananthapuram , Kerala 695551 , India.

出版信息

Inorg Chem. 2018 Oct 1;57(19):11855-11858. doi: 10.1021/acs.inorgchem.8b02017. Epub 2018 Sep 20.

DOI:10.1021/acs.inorgchem.8b02017
PMID:30232885
Abstract

A new three-dimensional europium-based metal-organic framework has been synthesized with the newly designed ligand L (6-[1-(4-carboxyphenyl)-1 H-1,2,3-triazol-4-yl]nicotinic acid). This compound acts as a dual sensor for the phosphate anion and Fe ion in aqueous media. The mechanistic aspect of this selectivity and sensitivity was explored through several spectroscopic methods and then correlated with the corresponding structure.

摘要

一种新型的三维铕基金属有机骨架已通过新设计的配体 L(6-[1-(4-羧基苯基)-1H-1,2,3-三唑-4-基]烟酸)合成。该化合物在水相中充当磷酸根阴离子和 Fe 离子的双重传感器。通过几种光谱方法研究了这种选择性和灵敏度的机制方面,并与相应的结构相关联。

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