A Zn(II) Coordination Polymer for Fluorescent Turn-Off Selective Sensing of Heavy Metal Cation and Toxic Inorganic Anions.

A novel coordination polymer [Zn(atyha)] () (Hatyha = 2-(2-aminothiazole-4-yl)-2- hydroxyiminoacetic acid) was constructed by hydrothermal reaction of Zn with Hatyha ligand. CP exhibits a 2D (4,4)-connected topological framework with Schläfli symbol of {4·6}, where atyha anions serve as tridentate ligands, bridging with Zn through carboxylate, thiazole and oxime groups. CP displays a strong ligand-based photoluminescence at 390 nm in the solid state, and remains significantly structurally stable in water. Interestingly, it can be utilized as a fluorescent probe for selective and sensitive sensing of Fe, CrO and MnO through the fluorescent turn-off effect with limit of detection (LOD) of 3.66 × 10, 2.38 × 10 and 2.94 × 10 M, respectively. Moreover, the efficient recyclability for detection of Fe and CrO is better than that for MnO. The mechanisms of fluorescent quenching involve reversible overlap of UV-Vis absorption bands of the analytes (Fe, CrO and MnO) with fluorescence excitation and emission bands for CP , respectively.