Electrochemical Materials, Department of Material Sciences and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA, 02139, USA.
Electrochemical Materials, ETH Zurich, Department of Materials, Hoenggerbergring 64, 8049, Zurich, Switzerland.
Adv Mater. 2018 Nov;30(44):e1804098. doi: 10.1002/adma.201804098. Epub 2018 Sep 20.
In the goal of a sustainable energy future, either the energy efficiency of renewable energy sources is increased, day-to-day energy consumption by smart electronic feedback loops is managed in a more efficient way, or contribution to atmospheric CO is reduced. By defining a next generation of fast-response electrochemical CO sensors and materials, one can contribute to local monitoring of CO flows from industrial plants and processes, for energy management and building control or to track climate alterations. Electrochemical Li -garnet-based sensors with Li La Zr O solid electrolytes can reach notable 1 min response time at lowered operation temperatures to track 400-4000 ppm levels of CO when compared with state-of-the-art NASICON-based sensors. By using principles of redefining the electrode electrochemistry, it is demonstrated that Li La Zr Ta O can be used to alter its classic use as energy-storage function to gain additional functions such as CO tracking.
在可持续能源未来的目标中,人们要么提高可再生能源的能源效率,要么通过智能电子反馈回路更有效地管理日常能源消耗,要么减少对大气 CO 的贡献。通过定义下一代快速响应电化学 CO 传感器和材料,人们可以为从工业工厂和工艺中监测 CO 流量做出贡献,用于能源管理和建筑控制,或用于跟踪气候变化。与最先进的 NASICON 基传感器相比,基于 Li-La-Zr-O 固体电解质的 Li 石榴石基传感器可以在降低的工作温度下达到显著的 1 分钟响应时间,以跟踪 400-4000 ppm 水平的 CO。通过重新定义电极电化学原理,证明 Li-La-Zr-Ta-O 可以用于改变其作为储能功能的经典用途,以获得额外的功能,如 CO 跟踪。