通过布朗斯特酸催化实现醛的对映选择性顺式和反式烷氧基烯丙基化。
Enantioselective syn- and anti-Alkoxyallylation of Aldehydes via Brønsted Acid Catalysis.
机构信息
Department of Chemistry and Biochemistry , Auburn University , Auburn , Alabama 36849 , United States.
出版信息
Org Lett. 2018 Oct 5;20(19):6174-6177. doi: 10.1021/acs.orglett.8b02653. Epub 2018 Sep 26.
PMID:30256121
Abstract
A diastereo- and enantioselective alkoxyallylation via phosphoric acid catalysis was reported. Under the developed conditions, either 1,2- syn- or 1,2- anti-alkoxyallylation adducts were obtained in good yields with high enantioselectivities.
摘要
据报道，通过磷酸催化实现了非对映选择性和对映选择性烷氧基烯丙基化反应。在开发的条件下，以良好的收率和高对映选择性得到了 1,2-syn- 或 1,2-anti-烷氧基烯丙基化加合物。
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