Department of Physical-Chemistry, São Paulo State University, Araraquara, SP 14800-900, Brazil.
Sensors (Basel). 2018 Sep 25;18(10):3229. doi: 10.3390/s18103229.
In this study, individual nanofabricated SnO micro-disks, previously shown to exhibit exceptional sensitivity to NO, are investigated to further our understanding of gas sensing mechanisms. The SnO disks presenting different areas and thickness were isolated and electrically connected to metallic electrodes aided by a Dual Beam Microscope (SEM/FIB). While single micro-disk devices were found to exhibit short response and recovery times and low power consumption, large interconnected arrays of micro-disks exhibit much higher sensitivity and selectivity. The source of these differences is discussed based on the gas/solid interaction and transport mechanisms, which showed that thickness plays a major role during the gas sensing of single-devices. The calculated Debye length of the SnO disk in presence of NO₂ is reported for the first time.
在这项研究中,我们研究了先前表现出对 NO 具有非凡敏感性的单个纳米制造 SnO 微盘,以进一步了解气体传感机制。通过双束显微镜(SEM/FIB),将呈现不同面积和厚度的 SnO 圆盘分离并电连接到金属电极上。虽然单个微盘器件被发现具有短的响应和恢复时间以及低功耗,但大的互连微盘阵列表现出更高的灵敏度和选择性。基于气体/固体相互作用和传输机制讨论了这些差异的来源,结果表明厚度在单个器件的气体传感中起着主要作用。首次报道了存在 NO₂时 SnO 盘的德拜长度的计算结果。