Department of Engine Research , Korea Institute of Machinery and Materials , 156, Gajeongbuk-ro , Yuseong-gu, Daejeon 34103 , Republic of Korea.
Environ Sci Technol. 2018 Nov 6;52(21):12153-12161. doi: 10.1021/acs.est.8b03459. Epub 2018 Oct 16.
Physicochemical properties of pure tire wear particles (TWPs) were investigated in a laboratory. A tire simulator installed in an enclosing chamber was employed to eliminate artifacts caused by interfering particles during the generation and measurement of TWPs. TWP particulate matter (PM and PM) was correlated with tire speed ( r > 0.94) and load ( r > 0.99). Their mass size distributions showed that TWP mode diameters ranged between 3 and 4 μm (unimodal). Tire wear caused by slip events resulted in an increase in the number concentration (ca. 8.4 × 10 cm) of particles (mainly ultrafine particles (UFPs)) at low PM and PM values (1 and 2 μg m, respectively). During braking events, UFPs were emitted at an early stage, with an increase in number concentration (up to 1.1 × 10 cm); a high mass concentration (3.6 mg m) was observed at a later stage via the coagulation of early emitted UFPs and condensation. On the basis of morphology and elemental composition, TWPs generally had elongated (micrometer-scale) and round/irregular (submicrometer-scale) shapes and they were classified into C/Si-rich, heavy metal-containing, S-containing, and mineral-containing particles. This study determined that TWP emissions can vary with changes in driving condition.
实验室研究了纯轮胎磨损颗粒(TWP)的物理化学性质。采用安装在封闭室内的轮胎模拟器来消除在 TWP 生成和测量过程中由干扰颗粒引起的假象。TWP 颗粒物(PM 和 PM)与轮胎速度(r>0.94)和负载(r>0.99)相关。它们的质量粒度分布表明 TWP 模式直径在 3 到 4 μm 之间(单峰)。滑动事件引起的轮胎磨损导致在低 PM 和 PM 值(分别为 1 和 2 μg m)时颗粒(主要是超细颗粒(UFPs))数浓度(约 8.4×10 cm)增加。在制动事件中,UFPs 在早期阶段排放,数浓度增加(高达 1.1×10 cm);通过早期排放的 UFPs 的凝聚和凝结,在后期观察到高质量浓度(3.6 mg m)。根据形貌和元素组成,TWP 通常具有拉长的(微米级)和圆形/不规则的(亚微米级)形状,并分为富 C/Si、含重金属、含 S 和含矿物质颗粒。本研究确定 TWP 排放可以随驾驶条件的变化而变化。