Department of Chemical & Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore.
Department of Chemical & Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore.
Water Res. 2018 Dec 15;147:43-49. doi: 10.1016/j.watres.2018.09.040. Epub 2018 Sep 27.
Carbon quantum dots (CQDs), which are a fascinating class of nanostructured carbons, have recently attracted extensive attention in the field of membrane technologies for their applications in separation processes. This is because they possess two unique advantages. Their productions are facile and inexpensive, while their physicochemical properties such as ultra-small sizes, good biocompatibility, high chemical inertness, tunable hydrophilicity, rich surface functional groups and antifouling characteristics are highly desirable. Leveraging on these, researchers have explored their utilizations in various membrane designs for reverse osmosis (RO), ultrafiltration (UF), nanofiltration (NF), forward osmosis (FO), pressure retarded osmosis (PRO), membrane distillation (MD), and organic solvent nanofiltration (OSN) processes. In particular, CQDs have especially stimulated exploration in the field of water treatment by membrane technologies since biocompatibility of membrane materials is of utmost importance to ensure safety of drinking water. In addition, CQDs are in a favorable position for achieving unprecedented performance of membrane separation processes in water treatment, in the light of substantial efficiency enhancement and antifouling propensity as discovered in recent studies. In this article, we will review the progress in the development of CQD incorporated membranes with discussions on their challenges and perspectives.
碳量子点(CQDs)是一类引人注目的纳米结构碳材料,由于其在分离过程中的应用,最近在膜技术领域引起了广泛关注。这是因为它们具有两个独特的优势。它们的生产既简单又廉价,而其物理化学性质,如超小尺寸、良好的生物相容性、高化学惰性、可调亲水性能、丰富的表面官能团和抗污染特性,都是非常理想的。利用这些性质,研究人员已经探索了它们在各种膜设计中的应用,包括反渗透(RO)、超滤(UF)、纳滤(NF)、正渗透(FO)、压力延迟渗透(PRO)、膜蒸馏(MD)和有机溶剂纳滤(OSN)过程。特别是,由于膜材料的生物相容性对确保饮用水安全至关重要,CQDs 特别刺激了膜技术在水处理领域的探索。此外,鉴于最近的研究发现CQDs 在提高效率和抗污染倾向方面具有显著的优势,它们在水处理中的膜分离过程中具有实现前所未有的性能的有利条件。本文将综述 CQD 复合膜的发展进展,并讨论其面临的挑战和前景。