Tang Shaojian, Zhang Xia, Sun Jiayue, Niu Dawen, Chruma Jason J
Key Laboratory of Green Chemistry & Technology (MOE), College of Chemistry, Sino-British Materials Research Institute, College of Physical Sciences & Technology, and State Key Laboratory of Biotherapy, West China Hospital , Sichuan University , Chengdu , Sichuan 610064 , People's Republic of China.
Chem Rev. 2018 Oct 24;118(20):10393-10457. doi: 10.1021/acs.chemrev.8b00349. Epub 2018 Oct 10.
This review covers the use of 2-azaallyl anions, 2-azaallyl cations, and 2-azaallyl radicals in organic synthesis up through June 2018. Particular attention is paid to both foundational studies and recent advances over the past decade involving semistabilized and nonstabilized 2-azaallyl anions as key intermediates in various carbon-carbon and carbon-heteroatom bond-forming processes. Both transition-metal-catalyzed and transition-metal-free transformations are covered. Azomethine ylides, which have received significant attention elsewhere, are discussed briefly with the primary focus on critical comparisons with 2-azaallyl anions in regard to generation and use.
本综述涵盖了截至2018年6月2-氮杂烯丙基阴离子、2-氮杂烯丙基阳离子和2-氮杂烯丙基自由基在有机合成中的应用。特别关注了基础研究以及过去十年中涉及半稳定和非稳定2-氮杂烯丙基阴离子作为各种碳-碳和碳-杂原子键形成过程中的关键中间体的最新进展。涵盖了过渡金属催化和无过渡金属的转化反应。别处已受到大量关注的甲亚胺叶立德，将简要讨论，主要重点是在生成和用途方面与2-氮杂烯丙基阴离子的关键比较。
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