AA'-Stacked Trilayer Hexagonal Boron Nitride Membrane for Proton Exchange Membrane Fuel Cells.

Hexagonal boron nitride (h-BN) and graphene have emerged as promising materials for proton exchange membranes because of their high proton conductivity and chemical stability. However, the defects and grain boundaries generated during the growth and transfer of two-dimensional materials limit their practical applicability. Here, we report the fabrication of membrane electrode assemblies using large-area single-oriented AA'-stacked trilayer h-BN (3L-BN), which exhibits very few defects during the growth and transfer, as a proton exchange membrane for use in fuel cell systems. The fuel cell based on AA'-stacked 3L-BN showed a H permeation current density as low as 2.69 mA cm and an open circuit voltage (OCV) as high as 0.958 V; this performance is much superior to those for cells based on Nafion (3.7 mA cm and 0.942 V, respectively) and single-layer h-BN (10.08 mA cm and 0.894 V, respectively). Furthermore, the fuel cell with the AA'-stacked 3L-BN membrane almost maintained its original performance (OCV, maximum power density, and H permeation current density) even after 100 h of an accelerated stress test at 30% RH and 90 °C, while the fuel cells with the Nafion and single-layer BN membranes exhibited severely deteriorated performances. The stability of the cell based on the AA'-stacked 3L-BN membrane was better because the membrane prevented gas crossover and suppressed the generation of reactive radicals during cell operation.