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最近在催化串联反应方面的进展和四吡咯大环作为催化剂的潜在应用。

Recent Advances in Catalyzed Sequential Reactions and the Potential Use of Tetrapyrrolic Macrocycles as Catalysts.

机构信息

Laboratório de Bioinorgânica e Catálise, Departamento de Química, Centro Politécnico, Universidade Federal do Paraná (UFPR), Curitiba, Paraná 81531-990, Brazil.

出版信息

Molecules. 2018 Oct 28;23(11):2796. doi: 10.3390/molecules23112796.

Abstract

Complexes of porphyrins and of other similar tetrapyrrolic macrocycles are extensively explored as catalysts for different chemical processes, and the development of solid catalysts for heterogeneous processes using molecules with the ability to act as multifunctional catalysts in one-pot reactions is increasing and can lead to the wider use of this class of molecules as catalysts. This mini review focuses on the application of this class of complexes as catalysts in a variety of sequential one-pot reactions.

摘要

卟啉和其他类似的四吡咯大环配合物作为不同化学过程的催化剂得到了广泛的研究,使用具有在一锅反应中充当多功能催化剂能力的分子开发用于多相过程的固体催化剂的研究正在增加,并且可以导致更广泛地使用这类分子作为催化剂。本综述重点介绍了这类配合物作为催化剂在各种连续一锅反应中的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7519/6278483/c737f36e03da/molecules-23-02796-g001.jpg

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