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磁性纳米粒子作为均相催化剂载体应用的最新进展

Recent Advances in the Application of Magnetic Nanoparticles as a Support for Homogeneous Catalysts.

作者信息

Govan Joseph, Gun'ko Yurii K

机构信息

School of Chemistry and CRANN, Trinity College Dublin, Dublin 2, Ireland.

St. Petersburg National Research University of Information Technologies, Mechanics and Optics, St. Petersburg 197101, Russia.

出版信息

Nanomaterials (Basel). 2014 Apr 2;4(2):222-241. doi: 10.3390/nano4020222.

Abstract

Magnetic nanoparticles are a highly valuable substrate for the attachment of homogeneous inorganic and organic containing catalysts. This review deals with the very recent main advances in the development of various nanocatalytic systems by the immobilisation of homogeneous catalysts onto magnetic nanoparticles. We discuss magnetic core shell nanostructures (e.g., silica or polymer coated magnetic nanoparticles) as substrates for catalyst immobilisation. Then we consider magnetic nanoparticles bound to inorganic catalytic mesoporous structures as well as metal organic frameworks. Binding of catalytically active small organic molecules and polymers are also reviewed. After that we briefly deliberate on the binding of enzymes to magnetic nanocomposites and the corresponding enzymatic catalysis. Finally, we draw conclusions and present a future outlook for the further development of new catalytic systems which are immobilised onto magnetic nanoparticles.

摘要

磁性纳米颗粒是用于附着均相无机和有机催化剂的极具价值的基质。本综述探讨了通过将均相催化剂固定在磁性纳米颗粒上而开发各种纳米催化体系的最新主要进展。我们讨论了磁性核壳纳米结构(例如,二氧化硅或聚合物包覆的磁性纳米颗粒)作为催化剂固定的基质。然后我们考虑与无机催化介孔结构以及金属有机框架结合的磁性纳米颗粒。还综述了催化活性小分子和聚合物的结合。之后,我们简要讨论了酶与磁性纳米复合材料的结合以及相应的酶催化作用。最后,我们得出结论并对固定在磁性纳米颗粒上的新型催化体系的进一步发展提出未来展望。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5944/5304662/d0e4432e8625/nanomaterials-04-00222-g001.jpg

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