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中国广东省一个典型乡镇农田土壤中的重金属:存在与空间分布。

Heavy metals in agricultural soils from a typical township in Guangdong Province, China: Occurrences and spatial distribution.

机构信息

College of Resources and Environment, Yangtze University, Wuhan 430100, China; Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China; State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China.

College of Resources and Environment, Yangtze University, Wuhan 430100, China; Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China.

出版信息

Ecotoxicol Environ Saf. 2019 Jan 30;168:184-191. doi: 10.1016/j.ecoenv.2018.10.092. Epub 2018 Oct 30.

Abstract

To investigate contamination level, origins and spatial distribution characteristics of heavy metals (Cu, Pb, Zn, Hg, Ni, Cd, As, and Cr) in agricultural soils of Gaogang Town, a typical industrial transfer-undertaking region of the Pearl River Delta (PRD), China, a total of 162 surface soil samples were collected in August 2016 and determined using inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectrometry and atomic fluorescence spectrometry. Moreover, heavy metals contents were systematically analyzed by pollution index, enrichment factor, multivariate statistical approaches and geostatistical analysis. The results showed that the mean concentrations of Cd, Pb, Zn, Ni, Cu and Hg were higher than the soil background values of Guangdong Province, and the relatively high values of pollution index and enrichment factor indicated that these elements (Cd, Pb, Zn and Hg) had cumulative trends in soil. All results of multivariate statistical approaches and geostatistical analysis showed that pollution were heavily distributed in areas of industries, river and dense road network. The eight heavy metals in agricultural soils of Gaogang Town came from three different sources. Arsenic, Cr, Cu and Ni arose mainly from parent materials. Agricultural practices and traffic activities were the main sources of Cd, Pb and Zn. Mercury mainly came from industrial practices.

摘要

为了调查中国珠江三角洲(PRD)典型产业转移承接区——高岗镇农业土壤中重金属(Cu、Pb、Zn、Hg、Ni、Cd、As 和 Cr)的污染水平、来源和空间分布特征,本研究于 2016 年 8 月采集了 162 个表层土壤样品,并采用电感耦合等离子体质谱法、电感耦合等离子体发射光谱法和原子荧光光谱法进行了测定。此外,还通过污染指数、富集因子、多元统计方法和地统计学分析系统地分析了重金属含量。结果表明,Cd、Pb、Zn、Ni、Cu 和 Hg 的平均浓度均高于广东省土壤背景值,且污染指数和富集因子的较高值表明这些元素(Cd、Pb、Zn 和 Hg)在土壤中具有累积趋势。多元统计方法和地统计学分析的所有结果均表明,污染主要分布在工业区、河流和密集的道路网地区。高岗镇农业土壤中的这 8 种重金属来自 3 个不同的来源。砷(As)、铬(Cr)、铜(Cu)和镍(Ni)主要来源于母质。农业耕作和交通活动是 Cd、Pb 和 Zn 的主要来源。汞(Hg)主要来自工业活动。

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