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Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene-Imine [3 + 2] Annulation.
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C-C Bond Cleavage of α-Pinene Derivatives Prepared from Carvone as a General Strategy for Complex Molecule Synthesis.
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Hydroxyproline-derived pseudoenantiomeric [2.2.1] bicyclic phosphines: asymmetric synthesis of (+)- and (-)-pyrrolines.
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Enantioselective Phosphine-Catalyzed Formal [4+4] Annulation of α,β-Unsaturated Imines and Allene Ketones: Construction of Eight-Membered Rings.
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Amino Acid-Derived Bifunctional Phosphines for Enantioselective Transformations.
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Chiral aminophosphines derived from hydroxyproline and their application in allene-imine [4 + 2] annulation.
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Hydrodealkenylative Cleavage of C(sp)-C(sp) Bonds: Preparation of (1, 3)-3-Methylcyclohexan-1-ol.
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Synthesis through C(sp)-C(sp) Bond Scission in Alkenes and Ketones.
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Hydrodealkenylative C(sp)-C(sp) Bond Fragmentation Using Isayama-Mukaiyama Peroxidation.
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Halodealkenylation: Ozonolysis and Catalytic Fe with Vitamin C Convert C(sp)-C(sp) Bonds to C(sp)-Halide Bonds.
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Dealkenylative Functionalizations: Conversion of Alkene C(sp)-C(sp) Bonds into C(sp)-X Bonds via Redox-Based Radical Processes.
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Access to Enantiomerically Pure P-Stereogenic Primary Aminophosphine Sulfides under Reductive Conditions.
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Dealkenylative Alkynylation Using Catalytic Fe and Vitamin C.
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Phosphine-Catalyzed (4+1) Annulation: Rearrangement of Allenylic Carbamates to 3-Pyrrolines through Phosphonium Diene Intermediates.
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1
Bridged [2.2.1] bicyclic phosphine oxide facilitates catalytic γ-umpolung addition-Wittig olefination.
Chem Sci. 2018 Jan 18;9(7):1867-1872. doi: 10.1039/c7sc04381c. eCollection 2018 Feb 21.
2
Suppression of Arrhythmia by Enhancing Mitochondrial Ca Uptake in Catecholaminergic Ventricular Tachycardia Models.
JACC Basic Transl Sci. 2017 Dec;2(6):737-747. doi: 10.1016/j.jacbts.2017.06.008. Epub 2017 Nov 8.
3
Total Synthesis of the Sesquiterpenoid Periconianone A Based on a Postulated Biogenesis.
J Am Chem Soc. 2017 Nov 15;139(45):16096-16099. doi: 10.1021/jacs.7b10053. Epub 2017 Nov 2.
5
Scalable procedure for the fragmentation of hydroperoxides mediated by copper and iron tetrafluoroborate salts.
Org Biomol Chem. 2016 Jul 14;14(26):6197-200. doi: 10.1039/c6ob00941g. Epub 2016 Jun 7.
6
Phosphine-mediated Highly Enantioselective Spirocyclization with Ketimines as Substrates.
Angew Chem Int Ed Engl. 2016 May 23;55(22):6492-6. doi: 10.1002/anie.201600453. Epub 2016 Apr 15.
7
Catalytic Asymmetric Total Synthesis of (-)-Actinophyllic Acid.
J Am Chem Soc. 2016 Mar 16;138(10):3298-301. doi: 10.1021/jacs.6b00567. Epub 2016 Mar 4.
8
Catalyst-Controlled Switch in Chemo- and Diastereoselectivities: Annulations of Morita-Baylis-Hillman Carbonates from Isatins.
Angew Chem Int Ed Engl. 2016 Feb 5;55(6):2147-51. doi: 10.1002/anie.201510825. Epub 2016 Jan 11.

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