2-乙烯基苯胺与炔烃的自由基加成/环化反应：通过电子催化合成萘。
Radical Addition/Cyclization Reaction of 2-Vinylanilines with Alkynes: Synthesis of Naphthalenes via Electron Catalysis.
机构信息
Department of Chemistry and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui, 230601, China.
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601, China.
出版信息
Chem Asian J. 2018 Dec 18;13(24):3855-3858. doi: 10.1002/asia.201801496. Epub 2018 Nov 21.
A cascade radical addition/cyclization reaction of 2-vinylanilines with alkynes for the synthesis of biologically important naphthalene derivatives is reported. In this transformation, the in-situ-formed diazonium salts from 2-vinylanilines served as efficient aryl radical precursors and the reaction was run under metal-free conditions.
报道了一种 2-乙烯基苯胺与炔烃的级联自由基加成/环化反应，用于合成具有重要生物学意义的萘衍生物。在这种转化中，2-乙烯基苯胺原位形成的重氮盐作为有效的芳基自由基前体，反应在无金属条件下进行。
Zotero 插件