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稳定同位素参考物质正确使用指南。

A guide for proper utilisation of stable isotope reference materials.

作者信息

Meier-Augenstein Wolfram, Schimmelmann Arndt

机构信息

a School of Pharmacy and Life Sciences , Robert Gordon University , Aberdeen , UK.

b Department of Earth and Atmospheric Sciences , Indiana University , Bloomington , IN , USA.

出版信息

Isotopes Environ Health Stud. 2019 May;55(2):113-128. doi: 10.1080/10256016.2018.1538137. Epub 2018 Nov 8.

Abstract

Many scientific publications about stable isotope ratios suffer from flawed practices regarding calibration and normalisation of raw δ values in conjunction with prescribed δ values of reference materials. Violations of the identical treatment principle with regards to samples and standards (i.e. reference materials) and lack of adherence to SI-mandated and IUPAC-recommended nomenclature exacerbate the widespread problem of lackadaisical analytical practice and reporting. Science is supposed to strive for exactness, whereas ambiguity and jargon confound interdisciplinary communication. This contribution aims to expose typical misconceptions and avoidable errors and offers guidance toward the reproducible generation of isotope data, isotopic scale normalisation, and proper data reporting. We offer a comprehensive overview of sources of light stable isotope reference materials to best match sample matrices encountered by stable isotope practitioners with chemically similar reference materials.

摘要

许多关于稳定同位素比率的科学出版物在原始δ值的校准和归一化以及参考物质规定的δ值方面存在有缺陷的做法。在对待样品和标准品(即参考物质)时违反相同处理原则,以及不遵守国际单位制规定和国际纯粹与应用化学联合会推荐的命名法,加剧了普遍存在的分析操作不严谨和报告不规范的问题。科学应该追求精确性,而模糊性和行话会混淆跨学科交流。本论文旨在揭示典型的误解和可避免的错误,并为可重复生成同位素数据、同位素尺度归一化和正确的数据报告提供指导。我们全面概述了轻稳定同位素参考物质的来源,以便使稳定同位素从业者遇到的样品基质与化学性质相似的参考物质实现最佳匹配。

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