School of Chemistry and Food, Federal University of Rio Grande (FURG), km 8 - Itália Avenue, 96203-900 Rio Grande, Brazil.
School of Chemistry and Food, Federal University of Rio Grande (FURG), km 8 - Itália Avenue, 96203-900 Rio Grande, Brazil.
Int J Biol Macromol. 2019 Feb 15;123:210-220. doi: 10.1016/j.ijbiomac.2018.11.042. Epub 2018 Nov 9.
Chitosan exhibits outstanding properties, which allow a wide range of applications. For this reason, chitosan-based biomaterials have been developed over the years and, among these biomaterials, chitosan-based nanomaterials may significantly change the material properties, which could result in some exceptional features. Indeed, chitosan-based nanofibers have a larger surface area:volume ratio than the bulk materials at macro scale. Moreover, chitosan-based nanofibers could lead to enhanced porosity and mechanical properties, which could also improve surface functionalities, and consequently, the range of applications. However, the diversity in sources of raw materials and the production processes for the development of chitosan might provide distinct physicochemical characteristics. Because the varieties of chitosan have been limited in the most part the nanofibers synthesis, the current review describes an extensive research concerning the development of chitosan-based nanofibers and summarizes the different techniques for the nanofibers production; in addition to point out the effects of chitosan characteristics on the spinnability of the solution. Furthermore, the present review explores some potential studies in relation to the chitosan-based nanofibers applied to food technology, including active food packaging, nanofood carrier and enzyme immobilization.
壳聚糖具有优异的性能,使其得到广泛的应用。正因为如此,壳聚糖基生物材料近年来得到了发展,而在这些生物材料中,壳聚糖基纳米材料可能会显著改变材料的性质,从而产生一些特殊的性能。事实上,壳聚糖纳米纤维的比表面积与体积比大于宏观尺度上的块状材料。此外,壳聚糖纳米纤维可以提高多孔性和机械性能,还可以改善表面功能,从而扩大应用范围。然而,壳聚糖原材料来源和生产工艺的多样性可能会提供不同的物理化学特性。由于壳聚糖的种类在很大程度上限制了纳米纤维的合成,因此,目前的综述描述了广泛的关于壳聚糖基纳米纤维的研究,并总结了不同的纳米纤维生产技术;此外,还指出了壳聚糖特性对溶液可纺性的影响。此外,本综述还探讨了与壳聚糖基纳米纤维在食品技术中的应用相关的一些潜在研究,包括活性食品包装、纳米食品载体和酶固定化。