Samsung Advanced Institute of Technology, Samsung Electronics Co. Ltd, Yeongtong-gu, Suwon-si, Gyeonggi-do 16678, Republic of Korea.
Nanotechnology. 2019 Jan 25;30(4):045301. doi: 10.1088/1361-6528/aaecbd. Epub 2018 Nov 20.
A low-temperature laser crystallization is newly devised for producing polycrystalline silicon (poly-Si) thin films of low-loss, low surface roughness enough for nanoscale patterning, applicable to practical Si metasurface elements on complementary metal-oxide semiconductor (CMOS) electronic architectures in visible lights. The method is based on dielectric encapsulation of an amorphous Si film and subsequent laser-induced local crystallization. Such poly-Si thin film yields order-of-magnitude smaller surface roughness and grain size than those obtained with the conventional laser annealing processes. The mechanism of the formation of small and uniform crystalline grains during solidification is studied to ensure the smooth surfaces enough for nanoscale patterning. By obtaining root mean square of surface roughness <2.49 nm and extinction coefficient <4.8 × 10 at 550 nm, visible metasurface color-filter elements are experimentally demonstrated with the resonant transmission-peak efficiency approaching ∼85%. This low-loss poly-Si metasurface is favorably compatible with embedded CMOS electronic architectures in contrast to the conventional thermal annealing processes that often cause failure of electrical device functionalities due to delamination and material-property degradation problems. The proposed fabrication in this study provides a practical method for further development of various Si metasurfaces in the visible domain and their integration with CMOS electronic devices as well.
一种新设计的低温激光结晶法被用于生产低损耗、低表面粗糙度的多晶硅(poly-Si)薄膜,这些薄膜的表面粗糙度和晶粒尺寸足以满足纳米级图案化的要求,适用于互补金属氧化物半导体(CMOS)电子架构中的可见光范围内的实用硅亚表面元件。该方法基于非晶硅薄膜的介电封装和随后的激光诱导局部结晶。与传统的激光退火工艺相比,这种多晶硅薄膜的表面粗糙度和晶粒尺寸小一个数量级。研究了在凝固过程中形成小而均匀的晶核的机制,以确保表面足够光滑,足以进行纳米级图案化。通过获得均方根表面粗糙度<2.49nm 和消光系数<4.8×10 在 550nm 处,实验证明了具有接近 85%的共振透射峰效率的可见光亚表面颜色滤光元件。与传统的热退火工艺相比,这种低损耗的多晶硅亚表面与嵌入式 CMOS 电子架构非常兼容,因为传统的热退火工艺经常由于分层和材料性能退化问题导致电子器件功能失效。本研究提出的制造方法为进一步开发可见光域的各种硅亚表面及其与 CMOS 电子器件的集成提供了一种实用方法。