Niggemann Meike, Gao Shuang
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
Angew Chem Int Ed Engl. 2018 Dec 21;57(52):16942-16944. doi: 10.1002/anie.201810701. Epub 2018 Nov 25.
Ready for the open waters? Recent developments have fundamentally changed our knowledge of vinyl cation reactivity. The myth that they are too reactive for a predictable reaction design has been debunked, and the applicability of their most distinguished feature, namely their carbene-like reactivity, has taken a major leap forwards. Vinyl cations have thus matured into distinct reactive intermediates with a bright future ahead.
准备好迎接广阔的研究领域了吗？最近的进展从根本上改变了我们对乙烯基碳正离子反应活性的认识。那种认为它们反应活性过高而无法进行可预测反应设计的错误观念已被揭穿，而且它们最显著的特征，即类卡宾反应活性的适用性也有了重大飞跃。因此，乙烯基碳正离子已发展成为独特的反应中间体，前景光明。
