纳米机械运动在杂核四组分双催化剂机械中的协同串联催化作用。
Concurrent tandem catalysis enabled by nanomechanical motion in heteroleptic four-component dual-catalyst machinery.
机构信息
Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Technology, University of Siegen, Adolf-Reichwein-Str. 2, Siegen D-57068, Germany.
出版信息
Chem Commun (Camb). 2023 Apr 20;59(33):4915-4918. doi: 10.1039/d3cc00637a.
When the basic ligand 3 was added to the heteroleptic three-component slider-on-deck [Ag(1)(2)] (sliding frequency = 57 kHz), it operated as a moderate brake pad ( = 45 kHz). Due to motion in the resulting four-component slider-on-deck [Ag(1)(2)(3)], both ligand 3 and silver(I) were continuously exposed and became catalytically active in a concurrent tandem Michael addition/hydroalkoxylation.
当基本配体 3 被添加到杂三组分滑套[Ag(1)(2)]（滑动频率=57 kHz）中时，它充当了一个中等强度的刹车片（=45 kHz）。由于形成的四组分滑套[Ag(1)(2)(3)]中的运动，配体 3 和银（I）都被连续暴露出来，并在串联的迈克尔加成/烷氧基化反应中同时具有催化活性。
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