Rajasekaran Vishnu Verman, Paul Indrajit, Schmittel Michael
Center of Micro and Nanochemistry and Engineering, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str. 2, D-57068, Germany.
Chem Commun (Camb). 2020 Oct 22;56(84):12821-12824. doi: 10.1039/d0cc05578f.
Two dynamic slider-on-deck assemblies, i.e. a two-component threefold degenerate (k298 = 34.9 kHz) and a catenated three-component ninefold degenerate (k298 = 27.9 kHz) system, were quantitatively interconverted. Inspection of their computed structures revealed an allosteric effect on the sliding rates due to the spatial interaction between the components.
两个动态的甲板上滑块组件，即一个双组分三重简并（k298 = 34.9千赫兹）和一个连环三组分九重简并（k298 = 27.9千赫兹）系统，被定量地相互转换。对其计算结构的检查揭示了由于各组分之间的空间相互作用而对滑动速率产生的变构效应。
