α-重氮酰胺与（二乙酰氧基碘）苯和胺的分子间乙酰氧基氨基烷基化反应
Intermolecular Acetoxyaminoalkylation of α-Diazo Amides with (Diacetoxyiodo)benzene and Amines.
作者信息
Döben Nadine, Yan Hong, Kischkewitz Marvin, Mao Jincheng, Studer Armido
机构信息
Institute of Organic Chemistry , University of Münster , Corrensstrasse 40 , 48149 Münster , Germany.
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation , Southwest Petroleum University , Chengdu 610500 , P. R. China.
出版信息
Org Lett. 2018 Dec 21;20(24):7933-7936. doi: 10.1021/acs.orglett.8b03504. Epub 2018 Dec 12.
Multicomponent reactions of diazo compounds have attracted much attention in recent years. Such transformations are generally conducted by applying transition metal catalysis and involve the corresponding metal carbenes as key intermediates. In this letter, a metal-free three-component intermolecular acetoxyaminoalkylation of α-diazo amides with tertiary aryl amines and (diacetoxyiodo)benzene is presented.
近年来，重氮化合物的多组分反应备受关注。此类转化反应通常通过过渡金属催化进行，且涉及相应的金属卡宾作为关键中间体。在本信函中，我们报道了一种无金属条件下，α-重氮酰胺与叔芳基胺及（二乙酰氧基碘）苯之间的分子间乙酰氧基氨基烷基化三组分反应。
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