Departamento de Química Orgánica y Química Inorgánica, Universidad de Alcalá (IQAR), 28805-Alcalá de Henares, Madrid, Spain.
Laboratorio de Catálisis Homogénea, Unidad Asociada al CSIC CIQSO-, Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, 21007-, Huelva, Spain.
Chem Asian J. 2019 Feb 1;14(3):329-343. doi: 10.1002/asia.201801559. Epub 2019 Jan 16.
Organoboron compounds have become one of the most versatile building blocks in organic synthesis owing to their accessible and efficient conversion into many different functional groups. In particular, alkenyl boronates have received a great deal of attention as very reactive substrates in Suzuki-Miyaura cross-coupling reactions. Accordingly, efforts towards the development of efficient methods to prepare this type of compound are ongoing. In this contribution, the progress in the search for synthetic routes for alkenyl boronates and their use in a variety of organic transformations is accounted.
有机硼化合物由于其可及且高效的转化为多种不同官能团的能力，已成为有机合成中用途最广泛的构建模块之一。特别是烯基硼酸酯作为 Suzuki-Miyaura 交叉偶联反应中非常活泼的底物，受到了极大的关注。因此，人们一直在努力开发有效的方法来制备这种化合物。本贡献总结了寻找合成烯基硼酸酯的方法及其在各种有机转化中的应用的研究进展。
