Buss Bonnie L, Miyake Garret M
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1101, United States.
Chem Mater. 2018 Jun 26;30(12):3931-3942. doi: 10.1021/acs.chemmater.8b01359. Epub 2018 Mar 25.
Photoinduced controlled radical polymerizations (CRPs) have provided a variety of approaches for the synthesis of polymers possessing targeted structures, compositions, and functionalities with the added capability for spatial and temporal control, presenting the potential for new materials development. However, the scalability and reliability of these systems can be limited as a consequence of dependence on uniform irradiation of the reaction to produce well-defined products. In this perspective, we highlight the utility and promise of photo-CRP approaches through an overview of the adaptation of these methodologies to photo-flow reactor systems. Special emphasis is placed on the current state-of-the-art in polymerization scalability, reactor design, and polymer scope.
光诱导可控自由基聚合（CRP）为合成具有目标结构、组成和功能的聚合物提供了多种方法，同时还具备空间和时间控制能力，展现了开发新材料的潜力。然而，由于依赖反应的均匀辐照来制备结构明确的产物，这些体系的可扩展性和可靠性可能会受到限制。从这个角度出发，我们通过概述这些方法在光流反应器系统中的应用，突出了光CRP方法的实用性和前景。特别强调了聚合反应可扩展性、反应器设计和聚合物范围方面的当前技术水平。
