多孔有机聚合物：光催化水分解的新兴平台。

Xu Chen, Zhang Weijie, Tang Juntao, Pan Chunyue, Yu Guipeng

Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, College of Chemistry and Chemical Engineering, Central South University, Changsha, China.

Front Chem. 2018 Dec 4;6:592. doi: 10.3389/fchem.2018.00592. eCollection 2018.

Porous organic polymers (POPs), known for its high surface area and abundant porosity, can be easily designed and constructed at the molecular level. The POPs offer confined molecular spaces for the interplay of photons, excitons, electrons and holes, therefore featuring great potential in catalysis. In this review, a brief summary on the recent development of some current state-of-the-art POPs for photocatalytic water splitting and their design principles and synthetic strategies as well as relationship between structure and photocatalytic hydrogen or oxygen evolution performance are presented. Future prospects including research directions are also proposed, which may provide insights for developing POPs for photocatalytic water splitting with our expectations.

多孔有机聚合物（POPs）以其高比表面积和丰富的孔隙率而闻名，能够在分子水平上轻松设计和构建。POPs为光子、激子、电子和空穴的相互作用提供了受限的分子空间，因此在催化领域具有巨大潜力。在本综述中，简要总结了一些用于光催化水分解的当前最先进的POPs的最新进展、它们的设计原理和合成策略，以及结构与光催化析氢或析氧性能之间的关系。还提出了包括研究方向在内的未来展望，这可能为按我们的期望开发用于光催化水分解的POPs提供见解。