Zhang Guigang, Lan Zhi-An, Wang Xinchen
State Key Laboratory of Photocatalysis on Energy and Environment , College of Chemistry , Fuzhou University , Fuzhou 350002 , China . Email:
Chem Sci. 2017 Aug 1;8(8):5261-5274. doi: 10.1039/c7sc01747b. Epub 2017 Jun 6.
Graphitic carbon nitride based polymers, being metal-free, accessible, environmentally benign and sustainable, have been widely investigated for artificial photosynthesis in recent years for the photocatalytic splitting of water to produce hydrogen fuel. However, the photocatalytic stoichiometric splitting of pure water into H and O with a molecular ratio of 2 : 1 is far from easy, and is usually hindered by the huge activation energy barrier and sluggish surface redox reaction kinetics. Herein, we provide a concise overview of cocatalyst modified graphitic carbon nitride based photocatalysts, with our main focus on the modulation of the water splitting redox reaction kinetics. We believe that a timely and concise review on this promising but challenging research topic will certainly be beneficial for general readers and researchers in order to better understand the property-activity relationship towards overall water splitting, which could also trigger the development of new organic architectures for photocatalytic overall water splitting through the rational control of surface chemistry.
基于石墨相氮化碳的聚合物无金属、易获取、环境友好且可持续,近年来在人工光合作用用于光催化分解水以生产氢燃料方面受到了广泛研究。然而,将纯水以2:1的分子比光催化化学计量分解为H₂和O₂并非易事,通常会受到巨大的活化能垒和缓慢的表面氧化还原反应动力学的阻碍。在此,我们简要概述了助催化剂修饰的基于石墨相氮化碳的光催化剂,主要关注水分解氧化还原反应动力学的调控。我们认为,对这一有前景但具有挑战性的研究课题进行及时且简洁的综述,对于普通读者和研究人员更好地理解全水分解的性质-活性关系肯定是有益的,这也可能通过合理控制表面化学来推动用于光催化全水分解的新型有机结构的开发。