Center of Basic Molecular Science (CBMS), Department of Chemistry , Tsinghua University , Beijing 100084 , China.
Chem Rev. 2019 Feb 27;119(4):2876-2953. doi: 10.1021/acs.chemrev.8b00404. Epub 2018 Dec 19.
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique characteristics and outstanding catalytic performance in addition to being cheap and earth-abundant. Hydride transfer processes are involved in a broad range of organic transformations that allow the facile preparation of various useful chemicals and synthetic building blocks. These reactions have continuously received great attention both from academia and industry. In this perspective, we review homogeneous cobalt-catalyzed hydride transfer reactions according to the classified reaction types and provide a comprehensive overview of the design, synthesis, and reactivity of cobalt catalysts, their catalytic applications, and reaction mechanisms.
钴由于其独特的性质和在均相催化中优异的催化性能，加之价格低廉且在地壳中含量丰富，因此越来越受到关注。氢化物转移过程涉及广泛的有机转化，这些转化可以方便地制备各种有用的化学品和合成砌块。这些反应一直受到学术界和工业界的极大关注。在这篇观点文章中，我们根据分类反应类型综述了均相钴催化的氢化物转移反应，并全面概述了钴催化剂的设计、合成和反应性、它们的催化应用和反应机理。
