Moon Sanghun, Nishii Yuji, Miura Masahiro
Org Lett. 2019 Jan 4;21(1):233-236. doi: 10.1021/acs.orglett.8b03675. Epub 2018 Dec 21.
A rhodium-catalyzed direct C-H arylation of naphthalene and anthracene was developed with the assistance of a thioether directing group. The reaction proceeded with exclusive peri-selectivity, and the series of coupling products were readily transformed into the corresponding sulfur-containing polyaromatics. Charge-transport properties of the provided dithiapyrenes were evaluated by computational studies.
在硫醚导向基团的辅助下，开发了一种铑催化的萘和蒽的直接C-H芳基化反应。该反应以专一的周位选择性进行，并且一系列偶联产物很容易转化为相应的含硫多环芳烃。通过计算研究评估了所提供的二硫代芘的电荷传输性质。
