Li Ruiping, Cheng Yingchun, Huang Wei
Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing, 211816, P. R. China.
Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), 127 West Youyi Road, Xi'an, Shaanxi, 710072, P. R. China.
Small. 2018 Nov;14(45):e1802091. doi: 10.1002/smll.201802091. Epub 2018 Sep 14.
Since the discovery of graphene, 2D materials with various properties have gained increasing attention in fields such as novel electronic, optic, spintronic, and valleytronic devices. As an important derivative of 2D materials, Janus 2D materials, such as Janus transition metal chalcogenides (TMDs), have become a research hot spot in recent years. Janus 2D materials with mirror asymmetry display novel properties, such as the Rashba effect and normal piezoelectric polarization, providing great promise for their application in sensors, actuators, and other electromechanical devices. Here, the current theoretical and experimental progresses made in the development of Janus 2D TMDs, including their structure and stability, electronic properties, fabrication, and the results of their characterization are reported. Finally, the future prospects for the further development of Janus 2D materials are considered.
自石墨烯被发现以来,具有各种特性的二维材料在新型电子、光学、自旋电子学和谷电子学等领域越来越受到关注。作为二维材料的一种重要衍生物,诸如Janus过渡金属硫族化合物(TMDs)等Janus二维材料近年来已成为研究热点。具有镜像不对称性的Janus二维材料展现出诸如Rashba效应和正常压电极化等新奇特性,这为它们在传感器、致动器及其他机电设备中的应用带来了巨大前景。在此,报道了Janus二维TMDs开发过程中当前取得的理论和实验进展,包括其结构与稳定性、电子特性、制备方法以及表征结果。最后,探讨了Janus二维材料进一步发展的未来前景。